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Nanjing, __ capital of Jiangsu Province, has _long history.

A.
a, a
B.
the, 不填
C.
the, a
D.
不填, the

C
解析：
the定冠詞表示特指，the capital of…表示···的首都或省會，不定冠詞a表示泛指用在輔音音素開頭的單詞之前。

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